Chemistry and related sciences

Question about Flame Photometry

Dear all,

I want to ask a question:

Should the Calibration graph for the Flame Photometry (direct-Intensity method)
be plotted as a straight line or a curve?

Thanks for you all the kind help!!

Comments (2)




2 Responses to “Question about Flame Photometry”

  1. admin says:

    In <1994Apr15.20383…@hkpv17.hkp.hk> cci…@hkpv17.hkp.hk writes:
    >Dear all,
    >I want to ask a question:
    >Should the Calibration graph for the Flame Photometry (direct-Intensity method)
    >be plotted as a straight line or a curve?
    >Thanks for you all the kind help!!

    It depends on the exakt conditions, including things like instrument type,
    flame conditions, element, concentration range etc.

    But as a general hint from my own experience:
    If your calibration standards differ not more than one to ten and you are
    measuring in the optimal concentration range for the element/instrument,
    you should expect a linear calibration. If not, everything is possible.

    —————————- <- cut here -> —————————-
    rolf elak  r…@nite.toppoint.de | Disclaimer:  Neither my employers
    D-24114 kiel                    | opinions nor my own. Just a road-
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  2. admin says:

    > Should the Calibration graph for the Flame Photometry (direct-Intensity
    > method) be plotted as a straight line or a curve?

    > Thanks for you all the kind help!!

    For reasons of accuracy you should always choose the linear range for  
    calibration. If the calibration plot shows a curve, your calibration range  
    is probably too wide. Split up this range into smaller ones. Each single  
    one will probably show a linear plot. Or use a smaller concentration as  
    your highest point of calibration. As far as I know there are only very  
    few elements that don’t show a linear correlation between concentration  
    and signal at all, even at very low concentrations.

    So long,
            Rainer

    Rainer Hofmann                             rhofm…@goffy.freinet.de
    Voice: ++49 761 4764055                    MausNet: Rainer Hofmann @FR
    Fax:   ++49 761 4764083
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