I’m a born-again over-forty model rocket enthusiast. In the US, model
rocket engines are legal and sold ready-made. For those of us who quit
rockets when we discovered girls, then decided years later that rockets
were far less dangerous, there are spiffy fiberglass engines with
graphite nozzles and ammonium perchlorate composite propellants. It’s
getting to be like consumer aerospace, or that is a popular
characterization. We don’t make engines, or mix propellants, BTW. (We
pay good money for fire insurance, why invalidate it?)
Anyway, to get to the question. Several decades ago, I "experimented"
with ammonium perchlorate composites, and couldn’t find a mixture that
wasn’t shock, friction, and temperature sensitive. I then picked up a
book on perchlorates (I was a college chem major), which mentioned
several additives that were supposed to stabilize these mixtures
catalytically (e.g.; MnO2). Now I can see how a catalyst can make a
mixture *MORE* sensitive, by lowering an energy barrier. Can a catalyst
actually *STABILIZE* a mixture? If so, does anyone have a simple
explanation?
Thanks in advance,
-Larry C.
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